Showing posts with label Biogas. Show all posts
Showing posts with label Biogas. Show all posts

Thursday, August 27, 2009

BIOGAS in INTERNAL COMBUSTION ENGINE

1. S. I. Engines
The only adoption for a spark ignition engine is a gas (not gasoline!) carburetor to work at the supply pressure (just like an LPG conversion, but an evaporator would not be needed as the storage pressure is low). It is also a good idea to scrub the H2S (as it causes corrosion) and to derate the engine (unless you want to replace it each year if operating continuously).

Modification of S.I. Engine
S.I. engines can run completely on biogas, however, the engines are required to be started on petrol at the beginning, conversion of S.I. engine for the entry of biogas, throttling of intake air & advancing the ignition timing. Biogas can be admitted to S.I. engine through the intake manifold & air flow control valve can be provided on the air cleaner pipe connecting air cleaner & carburetor for throttling the intake air.
2. C.I.Engine:- .
iesel engines also need a gas carburetor and scrubbing, but require at least 10% diesel via the injectors for ignition (and cooling). The initial starting of diesel engine is done on pure diesel

Modification of C.I. Engine:–
C.I. engine can operate on dual fuel & the necessary engine modification include provision for the entry of biogas with intake air, provision of carburetor & system to reduce diesel supply, advanced injection timing. The entry of biogas and mixing of gas with intake air can be achieved by providing the mixing chamber below the air cleaner which facilitate through mixing of biogas with air before entering into the cylinder.
The arrangement is shown in fig. is largely used in stationary engine commercially available in India. The capacity of mixing chamber may be kept equal to the engine displacement volume. The pilot injection of cycle is required to be advanced for smooth and efficient running of engine on dual fuel. The admittance of biogas into the engine at the initial stage increases engine speed and therefore a suitable system reduces the diesel supply by actuating the control rack needs to be incorporated.There is a wide range of thoughts on what treatments should these biogases be subjected to before being used as fuel. Most operators simply remove the water present in the biogas, leaving it to the engine manufacturers to design engines which will cope with the impurities inevitably included in the biogas (significant maintenance costs);

other Operators are seriously evaluating maintenance costs against initial investments in biogas clean up technologies such as has been developed by Acrion Technologies (although Acrion's technologies are mainly aimed at biogas contaminant removal and separation into methane and carbon dioxide as feed stocks for a variety of commercial applications).

PRACTICAL DIFFICULTIES
To use the biogas as a fuel in SI engine there are some practical difficulties. It is not possible to compress the methane, separated from biogas by available method, because the gas could be liquefied through chilling below -161 0C. This process is adapted by installing the units required when there use of methane separated from biogas as a fuel. Since gas can not be compressed it requires large space for storage.

PERFORMANCE
1. In purification method, by reducing CO2 and moisture along H2S impurities in biogas, the engine performance is improved.
2. Effect of spark timing :-Biogas is slow burning fuel. Hence in order to get optimum engine performance, spark timing does not advance, and then combustion continues in major part of the expansion stroke. This reduces effective work done. By advancing, spark timing power is improved on low speed at partial throttle condition as well as high speed at full throttle condition.
EXHAUST EMMISSIONS
The exhaust emission contains three specific substances which contribute the air pollution, hydrocarbon, carbon monoxide &oxides of nitrogen. Hydrocarbons are the unburned fuel vapour coming out with the exhaust due to incomplete combustion. Hydrocarbon also occurring in crankcase by fuel evaporation. The emission of hydrocarbon is closely related to many design &operating factors like induction system, combustion chamber design, air fuel ratio, speed, load. Lean mixture lower hydrocarbon emission.Carbon monoxide occurs only in engine exhaust.

It is the product of incomplete combustion due to insufficient amount of air in air- fuel mixture. Some amount of CO is always present in the exhaust even at lean mixture. When the throttle is closed to reduce air supply at the time of starting the vehicle, maximum amount of CO is produced. Oxides of nitrogen are the combination of nitric oxide & nitrogen oxide &availability of oxygen are the two main reasons for the formation of oxides of nitrogen. The spark advance means lower peak combustion temperature. It causes high NO concentration in the exhaust. With biogas, co emission levels are low than that of gasoline.

Wednesday, August 12, 2009

Biomethane

Biomethane

Biomethane is "renewable natural gas" made from organic sources - which starts out as "biogas" but then is cleaned up, removing the impurities in the biogas, such as carbon dioxide and hydrogen sulfide (H2S).

"Cleaned-up" and ready for use in an onsite cogeneration or trigeneration power plant, the Biomethane could also be sold to a pipeline company and completely replace the "natural gas" that is typically transported to markets via the vast underground pipeline system.

Biomethane will some day replace the "methane" that is sold by the local gas companies. Biomethane has an unlimited supply, whereas the methane sold by gas companies has a limited supply. Biomethane is renewable, whereas the methane sold by your gas utility company is not renewable. Biomethane recovery, use and production generates "Greentags" or a "Renewable Energy Credit" for the owners and is GOOD for our environment. The production and use of the natural gas sold by the gas company does NOT generate these incentives and new revenue streams and is NOT good for our environment.

As previously mentioned, Biomethane is "naturally" produced from organic materials as they decay. Sources of Biomethane include; landfills, POTW's/Wastewaster Treatment Systems, and every tree or agricultural product that is no longer living. Biomethane also generated from animal operations where manure can be collected and the Biomethane is generated from anaerobic digesters where the manure decomposes.

Biomethane, after installation of the Biomethane equipment is essentially free, as opposed to buying natural gas, presently costing around $10.00/mmbtu. Methanogenesis, also called Biomethanation, is the production of CH4 and CO2 by biological processes that are carried out by methanogens.
Unlike the price of natural gas, which has been around $6.00/mmbtu to as high as $17.00/mmbtu this past year, Biomethane prices will tend to be more stable over the years as more and more Biomethane is produced, and produced in reliable and sustainable methods that can fuel the energy needs until a better fuel is found.

Biofuel

Biofuel

Biofuel is defined as solid, liquid or gaseous fuel obtained from relatively recently lifeless biological material and is different from relic fuels, which are derived from long dead biological material. Also, various plants and plant-derived materials are used for biofuel manufacturing.

Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking. Biofuel industries are expanding in Europe, Asia and the Americas. Recent technology developed at Los Alamos National Lab even allows for the conversion of pollution into renewable bio fuel. Agrofuels are biofuels which are produced from specific crops, rather than from waste processes such as landfill off-gassing or recycled vegetable oil.

There are two common strategies of producing liquid and gaseous agrofuels. One is to grow crops high in sugar (sugar cane, sugar beet, and sweet sorghum) or starch (corn/maize), and then use yeast fermentation to produce ethyl alcohol (ethanol). The second is to grow plants that contain high amounts of vegetable oil, such as oil palm, soybean, algae, jatropha, or pongamia pinnata.

When these oils are heated, their viscosity is reduced, and they can be burned directly in a diesel engine, or they can be chemically processed to produce fuels such as biodiesel. Wood and its byproducts can also be converted into biofuels such as woodgas, methanol or ethanol fuel. It is also possible to make cellulosic ethanol from non-edible plant parts, but this can be difficult to accomplish economically.

Types of Bio Fuels

Types of Bio Fuels

First generation biofuels'First-generation biofuels' are biofuels made from sugar, starch, vegetable oil, or animal fats using conventional technology. The basic feedstocks for the production of first generation biofuels are often seeds or grains such as wheat, which yields starch that is fermented into bioethanol, or sunflower seeds, which are pressed to yield vegetable oil that can be used in biodiesel. These feedstocks could instead enter the animal or human food chain, and as the global population has risen their use in producing biofuels has been criticised for diverting food away from the human food chain, leading to food shortages and price rises.

The most common first generation biofuels are listed below.

Vegetable oilMain article:

Vegetable oil used as fuelEdible vegetable oil is generally not used as fuel, but lower quality oil can be used for this purpose. Used vegetable oil is increasingly being processed into biodiesel, or (more rarely) cleaned of water and particulates and used as a fuel. To ensure that the fuel injectors atomize the fuel in the correct pattern for efficient combustion, vegetable oil fuel must be heated to reduce its viscosity to that of diesel, either by electric coils or heat exchangers. This is easier in warm or temperate climates. MAN B&W Diesel, Wartsila and Deutz AG offer engines that are compatible with straight vegetable oil, without the need for after-market modifications. Vegetable oil can also be used in many older diesel engines that do not use common rail or unit injection electronic diesel injection systems. Due to the design of the combustion chambers in indirect injection engines, these are the best engines for use with vegetable oil.

This system allows the relatively larger oil molecules more time to burn. However, a handful of drivers have experienced limited success with earlier pre-"pumped use" VW TDI engines and other similar engines with direct injection.BiodieselMain articles: Biodiesel and Biodiesel around the worldBiodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to fossil/mineral diesel. Its chemical name is fatty acid methyl (or ethyl) ester (FAME). Oils are mixed with sodium hydroxide and methanol (or ethanol) and the chemical reaction produces biodiesel (FAME) and glycerol. One part glycerol is produced for every 10 parts biodiesel. Feedstocks for biodiesel include animal fats, vegetable oils, soy, rapeseed, jatropha, mahua, mustard, flax, sunflower, palm oil, hemp, field pennycress, pongamia pinnata and algae. Pure biodiesel (B100) is by far the lowest emission diesel fuel.

Although liquefied petroleum gas and hydrogen have cleaner combustion, they are used to fuel much less efficient petrol engines and are not as widely available.Biodiesel can be used in any diesel engine when mixed with mineral diesel.
The majority of vehicle manufacturers limit their recommendations to 15% biodiesel blended with mineral diesel. In some countries manufacturers cover their diesel engines under warranty for B100 use, although Volkswagen of Germany, for example, asks drivers to check by telephone with the VW environmental services department before switching to B100. B100 may become more viscous at lower temperatures, depending on the feedstock used, requiring vehicles to have fuel line heaters.
In most cases, biodiesel is compatible with diesel engines from 1994 onwards, which use 'Viton' (by DuPont) synthetic rubber in their mechanical injection systems. Electronically controlled 'common rail' and 'pump duse' type systems from the late 1990s onwards may only use biodiesel blended with conventional diesel fuel. These engines have finely metered and atomized multi-stage injection systems are very sensitive to the viscosity of the fuel. Many current generation diesel engines are made so that they can run on B100 without altering the engine itself, although this depends on the fuel rail design. NExBTL is suitable for all diesel engines in the world since it overperforms DIN EN 590 standards.Since biodiesel is an effective solvent and cleans residues deposited by mineral diesel, engine filters may need to be replaced more often, as the biofuel dissolves old deposits in the fuel tank and pipes.
It also effectively cleans the engine combustion chamber of carbon deposits, helping to maintain efficiency. In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations. Biodiesel is also an oxygenated fuel, meaning that it contains a reduced amount of carbon and higher hydrogen and oxygen content than fossil diesel. This improves the combustion of fossil diesel and reduces the particulate emissions from un-burnt carbon.In the USA, more than 80% of commercial trucks and city buses run on diesel. The emerging US biodiesel market is estimated to have grown 200% from 2004 to 2005. "By the end of 2006 biodiesel production was estimated to increase fourfold [from 2004] to more than 1 billion gallons.

BioalcoholsBiologically produced alcohols, most commonly ethanol, and less commonly propanol and butanol, are produced by the action of microorganisms and enzymes through the fermentation of sugars or starches (easiest), or cellulose (which is more difficult). Biobutanol (also called biogasoline) is often claimed to provide a direct replacement for gasoline, because it can be used directly in a gasoline engine (in a similar way to biodiesel in diesel engines).Butanol is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with butanol as the only liquid product. Butanol will produce more energy and allegedly can be burned "straight" in existing gasoline engines (without modification to the engine or car), and is less corrosive and less water soluble than ethanol, and could be distributed via existing infrastructures. DuPont and BP are working together to help develop Butanol. E. coli have also been successfully engineered to produce Butanol by hijacking their amino acid metabolism.Ethanol fuel is the most common biofuel worldwide, particularly in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch that alcoholic beverages can be made from (like potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches, fermentation of the sugars, distillation and drying. The distillation process requires significant energy input for heat (often unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse, the waste left after sugar cane is pressed to extract its juice, can also be used more sustainably).Ethanol can be used in petrol engines as a replacement for gasoline; it can be mixed with gasoline to any percentage. Most existing automobile petrol engines can run on blends of up to 15% bioethanol with petroleum/gasoline. Gasoline with ethanol added has higher octane, which means that your engine can typically burn hotter and more efficiently. In high altitude (thin air) locations, some states mandate a mix of gasoline and ethanol as a winter oxidizer to reduce atmospheric pollution emissions.Ethanol fuel has less BTU energy content, which means it takes more fuel (volume and mass) to produce the same amount of work. An advantage of ethanol is that is has a higher octane rating than ethanol-free gasoline available at roadside gas stations and ethanol's higher octane rating allows an increase of an engine's compression ratio for increased thermal efficiency.. Very-expensive aviation gasoline (Avgas) is 100 octane made from 100% petroleum with toxic tetra-ethyl lead added to raise the octane number. The high price of zero-ethanol Avgas does not include federal-and-state road-use taxes.Ethanol is very corrosive to fuel systems, rubber hoses and gaskets, aluminum, and combustion chambers. Therefore, it is illegal to use fuels containing alcohol in aircraft (although at least one model of ethanol-powered aircraft has been developed, the Embraer EMB 202 Ipanema). Ethanol also corrodes fiberglass fuel tanks such as used in marine engines. For higher ethanol percentage blends, and 100% ethanol vehicles, engine modifications are required.It is the hygroscopic (water loving) nature of relatively polar ethanol that can promote corrosion of existing pipelines and older fuel delivery systems. To characterize ethanol itself as a corrosive chemical is somewhat misleading and the context in which it can be indirectly corrosive, somewhat narrow; i.e., limited to effects upon existing pipelines designed for petroleum transport.Corrosive ethanol cannot be transported in petroleum pipelines, so more-expensive over-the-road stainless-steel tank trucks increase the cost and energy consumption required to deliver ethanol to the customer at the pump.In the current alcohol-from-corn production model in the United States, considering the total energy consumed by farm equipment, cultivation, planting, fertilizers, pesticides, herbicides, and fungicides made from petroleum, irrigation systems, harvesting, transport of feedstock to processing plants, fermentation, distillation, drying, transport to fuel terminals and retail pumps, and lower ethanol fuel energy content, the net energy content value added and delivered to consumers is very small. And, the net benefit (all things considered) does little to reduce un-sustainable imported oil and fossil fuels required to produce the ethanol.Although ethanol-from-corn and other food stocks has implications both in terms of world food prices and limited, yet positive energy yield (in terms of energy delivered to customer/fossil fuels used), the technology has lead to the development of cellulosic ethanol. According to a joint research agenda conducted through the U.S. Department of Energy, the fossil energy ratios (FER) for cellulosic ethanol, corn ethanol, and gasoline are 10.3, 1.36, and 0.81, respectively.Many car manufacturers are now producing flexible-fuel vehicles (FFV's), which can safely run on any combination of bioethanol and petrol, up to 100% bioethanol. They dynamically sense exhaust oxygen content, and adjust the engine's computer systems, spark, and fuel injection accordingly. This adds initial cost and ongoing increased vehicle maintenance. Efficiency falls and pollution emissions increase when FFV system maintenance is needed (regardless of the fuel mix being used), but not performed (as with all vehicles). FFV internal combustion engines are becoming increasingly complex, as are multiple-propulsion-system FFV hybrid vehicles, which impacts cost, maintenance, reliability, and useful lifetime longevity.Alcohol mixes with both petroleum and with water, so ethanol fuels are often diluted after the drying process by absorbing environmental moisture from the atmosphere. Water in alcohol-mix fuels reduces efficiency, makes engines harder to start, causes intermittent operation (sputtering), and oxidizes aluminum (carburetors) and steel components (rust).Even dry ethanol has roughly one-third lower energy content per unit of volume compared to gasoline, so larger / heavier fuel tanks are required to travel the same distance, or more fuel stops are required. With large current un-sustainable, non-scalable subsidies, ethanol fuel still costs much more per distance traveled than current high gasoline prices in the United States.Methanol is currently produced from natural gas, a non-renewable fossil fuel. It can also be produced from biomass as biomethanol. The methanol economy is an interesting alternative to the hydrogen economy, compared to today's hydrogen produced from natural gas, but not hydrogen production directly from water and state-of-the-art clean solar thermal energy processes.BioethersBio ethers (also referred to as fuel ethers or fuel oxygenates) are cost-effective compounds that act as octane enhancers. They also enhance engine performance, whilst significantly reducing engine wear and toxic exhaust emissions. Greatly reducing the amount of ground-level ozone, they contribute to the quality of the air we breathe.Biogas is produced by the process of anaerobic digestion of organic material by anaerobes. It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate, can be used as a biofuel or a fertilizer. In the UK, the National Coal Board experimented with microorganisms that digested coal in situ converting it directly to gases such as methane.Biogas contains methane and can be recovered from industrial anaerobic digesters and mechanical biological treatment systems. Landfill gas is a less clean form of biogas which is produced in landfills through naturally occurring anaerobic digestion. If it escapes into the atmosphere it is a potent greenhouse gas.Oils and gases can be produced from various biological wastes:• Thermal depolymerization of waste can extract methane and other oils similar to petroleum.• GreenFuel Technologies Corporation developed a patented bioreactor system that uses nontoxic photosynthetic algae to take in smokestacks flue gases and produce biofuels such as biodiesel, biogas and a dry fuel comparable to coal.SyngasMain article: GasificationSyngas, a mixture of carbon monoxide and hydrogen, is produced by partial combustion of biomass, that is, combustion with an amount of oxygen that is not sufficient to convert the biomass completely to carbon dioxide and water. Before partial combustion the biomass is dried, and sometimes pyrolysed.The resulting gas mixture, syngas, is itself a fuel. Using the syngas is more efficient than direct combustion of the original biofuel; more of the energy contained in the fuel is extracted.Syngas may be burned directly in internal combustion engines or turbines. The wood gas generator is a wood-fueled gasification reactor mounted on an internal combustion engine. Syngas can be used to produce methanol and hydrogen, or converted via the Fischer-Tropsch process to produce a synthetic diesel substitute, or a mixture of alcohols that can be blended into gasoline. Gasification normally relies on temperatures >700°C. Lower temperature gasification is desirable when co-producing biochar but results in a Syngas polluted with tar.Solid biofuelsExamples include wood, sawdust, grass cuttings, domestic refuse, charcoal, agricultural waste, non-food energy crops (see picture), and dried manure.When raw biomass is already in a suitable form (such as firewood), it can burn directly in a stove or furnace to provide heat or raise steam. When raw biomass is in an inconvenient form (such as sawdust, wood chips, grass, agricultural wastes), another option is to pelletize the biomass with a pellet mill. The resulting fuel pellets are easier to burn in a pellet stove.A problem with the combustion of raw biomass is that it emits considerable amounts of pollutants such as particulates and PAHs (polycyclic aromatic hydrocarbons). Even modern pellet boilers generates much more pollutants than oil or natural gas boilers. Pellets made from agricultural residues are usually worse than wood pellets, producing much larger emissions of dioxins and chlorophenols.Another solid biofuel is biochar, which is produced by biomass pyrolysis. Biochar pellets made from agricultural waste can substitute for wood charcoal. In countries where charcoal stoves are popular, this can reduce deforestation.Second generation biofuelsSupporters of biofuels claim that a more viable solution is to increase political and industrial support for, and rapidity of, second-generation biofuel implementation from non food crops, including cellulosic biofuels. Second-generation biofuel production processes can use a variety of non food crops. These include waste biomass, the stalks of wheat, corn, wood, and special-energy-or-biomass crops (e.g. Miscanthus). Second generation (2G) biofuels use biomass to liquid technology, including cellulosic biofuels from non food crops. Many second generation biofuels are under development such as biohydrogen, biomethanol, DMF, Bio-DME, Fischer-Tropsch diesel, biohydrogen diesel, mixed alcohols and wood diesel.Cellulosic ethanol production uses non food crops or inedible waste products and does not divert food away from the animal or human food chain. Lignocellulose is the "woody" structural material of plants. This feedstock is abundant and diverse, and in some cases (like citrus peels or sawdust) it is a significant disposal problem.Producing ethanol from cellulose is a difficult technical problem to solve. In nature, ruminant livestock (like cattle) eats grass and then use slow enzymatic digestive processes to break it into glucose (sugar). In cellulosic ethanol laboratories, various experimental processes are being developed to do the same thing, and then the sugars released can be fermented to make ethanol fuel. In 2009 scientists reported developing, using "synthetic biology", "15 new highly stable fungal enzyme catalysts that efficiently break down cellulose into sugars at high temperatures", adding to the 10 previously known. In addition, research conducted at TU Delft by Jack Pronk has shown that elephant yeast, when slightly modified can also create ethanol from non-edible ground sources (eg straw).The recent discovery of the fungus Gliocladium roseum points toward the production of so-called myco-diesel from cellulose. This organism was recently discovered in the rainforests of northern Patagonia and has the unique capability of converting cellulose into medium length hydrocarbons typically found in diesel fuel.Scientists also work on experimental recombinant DNA genetic engineering organisms that could increase biofuel potential.Third generation biofuelsAlgae fuelAlgae fuel, also called oilgae or third generation biofuel, is a biofuel from algae. Algae are low-input, high-yield feedstocks to produce biofuels. It produces 30 times more energy per acre than land crops such as soybeans. With the higher prices of fossil fuels (petroleum), there is much interest in algaculture (farming algae). One advantage of many biofuels over most other fuel types is that they are biodegradable, and so relatively harmless to the environment if spilled.The United States Department of Energy estimates that if algae fuel replaced all the petroleum fuel in the United States, it would require 15,000 square miles (38,849 square kilometers), which is roughly the size of Maryland.Second and third generation biofuels are also called advanced biofuels.Algae, such as Botryococcus braunii and Chlorella vulgaris, are relatively easy to grow, but the algal oil is hard to extract. There are several approaches, some of which work better than others. See: Prospects for the Biodiesel Industry.Biofuels by regionMain article: Biofuels by regionRecognizing the importance of implementing bioenergy, there are international organizations such as IEA Bioenergy, established in 1978 by the OECD International Energy Agency (IEA), with the aim of improving cooperation and information exchange between countries that have national programs in bioenergy research, development and deployment. The U.N. International Biofuels Forum is formed by Brazil, China, India, South Africa, the United States and the European Commission. The world leaders in biofuel development and use are Brazil, United States, France, Sweden and Germany

Bioenergy

Bioenergy

Bioenergy is renewable energy made available from materials derived from biological sources. In its most narrow sense it is a synonym to biofuel, which is fuel derived from biological sources. In its broader sense it includes biomass, the biological material used as a biofuel, as well as the social, economic, scientific and technical fields associated with using biological sources for energy. This is a common misconception, as bioenergy is the energy extracted from the biomass, as the biomass is the fuel and the bioenergy is the energy contained in the fuel.

Biomass is any organic material which has stored sunlight in the form of chemical energy. As a fuel it may include wood, wood waste, straw, manure, sugar cane, and many other byproducts from a variety of agricultural processes.

There is a slight tendency for the word bioenergy to be favoured in Europe compared with biofuel in North America.

Solid Biomass

Biomass is material derived from recently living organisms, which includes plants, animals and their byproducts. Manure, garden waste and crop residues are all sources of biomass. It is a renewable energy source based on the carbon cycle, unlike other natural resources such as petroleum, coal, and nuclear fuels.

Animal waste is a persistent and unavoidable pollutant produced primarily by the animals housed in industrial-sized farms.

There are also agricultural products being grown for biofuel production. These include corn, switchgrass, and soybeans, primarily in the United States; rapeseed, wheat and sugar beet primarily in Europe; sugar cane in Brazil; palm oil and miscanthus in Southeast Asia; sorghum and cassava in China; and jatropha in India. Hemp has also been proven to work as a biofuel. Biodegradable outputs from industry, agriculture, forestry and households can be used for biofuel production, using e.g. anaerobic digestion to produce biogas, gasification to produce syngas or by direct combustion. Examples of biodegradable wastes include straw, timber, manure, rice husks, sewage, and food waste. The use of biomass fuels can therefore contribute to waste management as well as fuel security and help to prevent or slow down climate change, although alone they are not a comprehensive solution to these problems.

Electricity generation from biomass

Electricity from sugarcane bagasse in Brazil
Sugar/Ethanol Plant located in Piracicaba, São Paulo State. This plant produces the electricity it needs from baggasse residuals from sugarcane left over by the milling process, and it sells the surplus electricity to the public grid.

Sucrose accounts for little more than 30% of the chemical energy stored in the mature plant; 35% is in the leaves and stem tips, which are left in the fields during harvest, and 35% are in the fibrous material (bagasse) left over from pressing.

The production process of sugar and ethanol in Brazil takes full advantage of the energy stored in sugarcane. Part of the baggasse is currently burned at the mill to provide heat for distillation and electricity to run the machinery. This allows ethanol plants to be energetically self-sufficient and even sell surplus electricity to utilities; current production is 600 MW for self-use and 100 MW for sale. This secondary activity is expected to boom now that utilities have been induced to pay "fair price "(about US$10/GJ or US$0.036/kWh) for 10 year contracts. This is approximately half of what the World Bank considers the reference price for investing in similar projects (see below). The energy is especially valuable to utilities because it is produced mainly in the dry season when hydroelectric dams are running low. Estimates of potential power generation from bagasse range from 1,000 to 9,000 MW, depending on technology. Higher estimates assume gasification of biomass, replacement of current low-pressure steam boilers and turbines by high-pressure ones, and use of harvest trash currently left behind in the fields. For comparison, Brazil's Angra I nuclear plant generates 657 MW.

Presently, it is economically viable to extract about 288 MJ of electricity from the residues of one tonne of sugarcane, of which about 180 MJ are used in the plant itself. Thus a medium-size distillery processing 1 million tonnes of sugarcane per year could sell about 5 MW of surplus electricity. At current prices, it would earn US$ 18 million from sugar and ethanol sales, and about US$ 1 million from surplus electricity sales. With advanced boiler and turbine technology, the electricity yield could be increased to 648 MJ per tonne of sugarcane, but current electricity prices do not justify the necessary investment. (According to one report, the World Bank would only finance investments in bagasse power generation if the price were at least US$19/GJ or US$0.068/kWh.)

Bagasse burning is environmentally friendly compared to other fuels like oil and coal. Its ash content is only 2.5% (against 30-50% of coal), and it contains no sulfur. Since it burns at relatively low temperatures, it produces little nitrous oxides. Moreover, bagasse is being sold for use as a fuel (replacing heavy fuel oil) in various industries, including citrus juice concentrate, vegetable oil, ceramics, and tyre recycling. The state of São Paulo alone used 2 million tonnes, saving about US$ 35 million in fuel oil imports.

Researchers working with cellulosic ethanol are trying to make the extraction of ethanol from sugarcane bagasse and other plants viable on an industrial scale.

Biochar

Biochar

Biochar is charcoal created by pyrolysis of biomass. The resulting charcoal-like material can be used as a soil improver to create terra preta, and is a form of carbon capture and storage. Charcoal is a stable solid and rich in carbon content, and thus, can be used to lock carbon in the soil. Biochar is of increasing interest because of concerns about climate change caused by emissions of carbon dioxide (CO2) and other greenhouse gases (GHG).

Biochar is a way for carbon to be drawn from the atmosphere and is a solution to reducing the global impact of farming (and in reducing the impact from all agricultural waste). Since biochar can sequester carbon in the soil for hundreds to thousands of years, it has received considerable interest as a potential tool to slow global warming. The burning and natural decomposition of trees and agricultural matter contributes a large amount of CO2 released to the atmosphere. Biochar can store this carbon in the ground, potentially making a significant reduction in atmospheric GHG levels; at the same time its presence in the earth can improve water quality, increase soil fertility, raise agricultural productivity and reduce pressure on old growth forests. Current biochar projects are small scale and make no significant impact on the overall global carbon budget, although expansion of this technique has been advocated as a geoengineering approach. Further research is in progress, notably by the University of Edinburgh, which has a dedicated research unit.

Uses of Biochar

Uses of Biochar


Carbon sink potential

Biochar can sequester carbon in the soil for hundreds to thousands of years. Modern biochar is being developed using pyrolysis to heat biomass in the absence of oxygen in kilns. Modern biochar production can be combined with biofuel production in a process that is exothermic (energy producing)—producing an output of 3-9 times more energy than invested, is carbon-negative—withdrawing CO2 from the atmosphere and rebuilds geological carbon sinks. This technique is advocated by prominent scientists such as James Hansen, an internationally-renowned climate scientist and head of NASA's Goddard Institute for Space Studies, and James Lovelock, creator of the Gaia hypothesis, for mitigation of global warming by greenhouse gas remediation.Biochar is a high-carbon, fine-grained residue which today is produced through modern pyrolysis processes. Pyrolysis is the direct thermal decomposition of biomass in the absence of oxygen to obtain an array of solid (biochar), liquid (bio-oil) and gas (syngas) products. The specific yield from the pyrolysis is dependent on process conditions, and can be optimized to produce either energy or biochar. Even when optimized to produce char rather than energy, the energy produced per unit energy input is higher than for corn ethanol.

Use as a carbon sink

Biochar can be used to sequester carbon on centurial or even millennial time scales. Plant matter absorbs CO2 from the atmosphere while growing. In the natural carbon cycle, plant matter decomposes rapidly after the plant dies, which emits CO2; the overall natural cycle is carbon neutral. Instead of allowing the plant matter to decompose, pyrolysis can be used to sequester the carbon in a much more stable form. Biochar thus removes circulating CO2 from the atmosphere and stores it in virtually permanent soil carbon pools, making it a carbon-negative process. In places like the Rocky Mountains, where beetles have been killing off vast swathes of pine trees, the utilization of pyrolysis to char the trees instead of letting them decompose into the atmosphere would offset substantial amounts of CO2 emissions. Although some organic matter is necessary for agricultural soil to maintain its productivity, much of the agricultural waste can be turned directly into biochar, bio-oil, and syngas. The use of pyrolysis also provides an opportunity for the processing of municipal waste into useful clean energy rather than increased problems with land space for storage.

Biochar is believed to have long mean residence times in the soil. While the methods by which biochar mineralizes (turns into CO2) are not completely known,evidence from soil samples in the Amazon shows large concentrations of black carbon (biochar) remaining after they were abandoned thousands of years ago. The amount of time the biochar will remain in the soil depends on the feedstock material, how charred the material is, the surface:volume ratio of the particles, and the conditions of the soil the biochar is placed in. Estimates for the residence time range from 100 to 10,000 yrs, with 5,000 being a common estimate. Lab experiments confirm a decrease in carbon mineralization with increasing temperature, so carefully controlled charring of plant matter can increase the soil residence time of the biochar C.

Under some circumstances, the addition of biochar to the soil has been found to accelerate the mineralization of the existing soil organic matter, but this would only reduce and not suppress the net benefit gained by sequestering carbon in the soil by this method. Furthermore, the suggested soil conditions for the integration of biochar are in heavily degraded tropical soils used for agriculture, not organic matter-rich boreal forest soils (as tested in the above reference).

Enhancing soil
In addition to its potential for carbon sequestration, biochar has numerous co-benefits when added to soil. It can prevent the leaching of nutrients out of the soil, increase the available nutrients for plant growth, increase water retention, and reduce the amount of fertilizer required. Additionally, it has been shown to decrease N2O (Nitrous oxide) and CH4 (methane) emissions from soil, thus further reducing GHG emissions. Biochar can be utilized in many applications as a replacement for or co-terminous strategy with other bioenergy production strategies. One of its most immediate uses is in switching from "slash-and-burn” to “slash-and-char” to prevent the rapid deforestation and subsequent degradation of soils.“Biochar sequestration does not require a fundamental scientific advance and the underlying production technology is robust and simple, making it appropriate for many regions of the world.” Johannes Lehmann, of Cornell University, estimates that pyrolysis will be cost feasible when the cost of a CO2 ton reaches $37, (as of the end of June 2008, CO2 is trading at $45/ton on the ECX) – so using pyrolysis for bioenergy production is feasible, even though it may be more expensive than fossil fuels at the moment.

Co-benefits for soil of pyrolysis

Biochar can be used as a soil amendment to increase plant growth yield, improve water quality, reduce soil emissions of GHGs, reduce leaching of nutrients, reduce soil acidity, and reduce irrigation and fertilizer requirements. These properties are very dependent on the properties of the biochar,and may depend on regional conditions including soil type, condition (depleted or healthy), temperature, and humidity. Modest additions of biochar to soil were found to reduce N2O emissions by up to 80% and completely suppress methane emissions.
Slash and charSwitching from slash-and-burn to slash-and-char techniques in Brazil can both decrease deforestation of the Amazon and increase the crop yield. Under the current method of slash-and-burn, only 3% of the carbon from the organic material is left in the soil.
Switching to slash-and-char can sequester up to 50% of the carbon in a highly stable form. Adding the biochar back into the soil rather than removing it all for energy production is necessary to avoid heavy increases in the cost and emissions from more required nitrogen fertilizers.Additionally, by improving the soil tilth, fertility, and productivity, the biochar enhanced soils can sustain agricultural production, whereas non-amended soils quickly become depleted of nutrients, and the fields are abandoned, leading to a continuous slash-and-burn cycle and the continued loss of tropical rainforest. Using pyrolysis to produce bio-energy also has the added benefit of not requiring infrastructure changes the way processing biomass for cellulosic ethanol does. Additionally, the biochar produced can be applied by the currently used tillage machinery or equipment used to apply fertilizer.

Energy production: bio-oil

Bio-oil can be used as a replacement for numerous applications where fuel oil is used, including fueling space heaters, furnaces, and boilers.Additionally, these biofuels can be used to fuel some combustion turbines and reciprocating engines, and as a source to create several chemicals. If bio-oil is used without modification, care must be taken to prevent emissions of black carbon and other particulates. Syngas and bio-oil can also be “upgraded” to transportation fuels like biodiesel and gasoline substitutes. If biochar is used for the production of energy rather than as a soil amendment, it can be directly substituted for any application that uses coal. pyrolysis also may be the most cost-effective way of producing electrical energy from biomaterial. Syngas can be burned directly, used as a fuel for gas engines and gas turbines, converted to clean diesel fuel through Fischer Tropsch or potentially used in the production of methanol and hydrogen.
Bio-oil has a much higher energy density than the raw biomass material.Mobile pyrolysis units can be used to lower the costs of transportation of the biomass itself if the biochar is returned to the soil and the syngas stream is used to power the process. Bio-oil contains organic acids which are corrosive to steel containers, has a high water vapor content which is detrimental to ignition, and, unless carefully cleaned, contains some biochar particles which can block injectors. The greatest potential for bio-oil seems to be its use in a bio-refinery, where compounds that are valuable chemicals, pesticides, pharmaceuticals or food additives are first extracted, and the remainder is either upgraded to fuel or reformed to syngas.

Production of biochar

Production of biochar

The yield of products from pyrolysis varies heavily with temperature. The lower the temperature, the more char is created per unit biomass. High temperature pyrolysis is also known as gasification, and produces primarily syngas from the biomass. The two main methods of pyrolysis are “fast” pyrolysis and “slow” pyrolysis. Fast pyrolysis yields 60% bio-oil, 20% biochar, and 20% syngas, and can be done in seconds, whereas slow pyrolysis can be optimized to produce substantially more char (~50%), but takes on the order of hours to complete. For typical inputs, the energy required to run a “fast” pyrolyzer is approximately 15% of the energy that it outputs.Modern pyrolysis plants can be run entirely off of the syngas created by the pyrolysis process and thus output 3-9 times the amount of energy required to run.Alternatively, microwave technology has recently been used to efficiently convert organic matter to biochar on an industrial scale, producing ~50% char.

The ancient method for producing biochar as a soil additive was the “pit” or “trench” method, which created terra preta, or dark soil. While this method is still a potential to produce biochar in rural areas, it does not allow the harvest of either the bio-oil or syngas, and releases a large amount of CO2, black carbon, and other GHGs (and potentially, toxins) into the air. Modern companies are producing commercial-scale systems to process agricultural waste, paper byproducts, and even municipal waste.

There are three primary methods for deploying a pyrolysis system. The first is a centralized system where all biomass in the region would be brought to a pyrolysis plant for processing. A second system would effectively mean a lower-tech pyrolysis kiln for each farmer or small group of farmers. A third system is a mobile system where a truck equipped with a pyrolyzer would be driven around to pyrolyze biomass. It would be powered using the syngas stream, return the biochar to the earth, and transport the bio-oil to a refinery or storage site. Whether a centralized system, a distributed system, or a mobile system is preferred is heavily dependent on the specific region. The cost of transportation of the liquid and solid byproducts, the amount of material to be processed in a region, and the ability to feed directly into the power grid are all factors to be considered when deciding on a specific implementation.

Unless crops are going to be dedicated to biochar production, the residue-to-product ratio (RPR) for the feedstock material is a useful gauge of the approximate amount of feedstock that can be obtained for pyrolysis after the primary product is harvested and the waste remains. The amount of crop residue available to be used for pyrolysis can be determined by using the RPR, and the collection factor (the percent of the residue not used for other things). For instance, Brazil harvests approximately 460Mt of sugar cane annually, with an RPR of 0.30, and a collection factor (CF) of 0.70 for the sugar cane tops, which are normally burned on the field. This translates into approximately 100Mt of residue which can be pyrolyzed to create energy and soil additives annually. Adding in the bagasse (sugar cane waste) (RPR=0.29 CF=1.0) which is currently burned inefficiently in boilers, raises the total to 230 Mt of pyrolysis feedstock just from sugar cane residues. Some plant residue, however, must remain on the soil to avoid heavily increased costs and emissions from nitrogen fertilizers.

Tuesday, August 11, 2009

Advantages of Biogas

Advantages of Biogas
1) It is light fuel gas.2) It mixes easily with the air.3) It is highly knocked resistant.4) Due to uniform distribution thermal efficiency is higher.5) Biogas has a high octane number.6) It reduces pollution.7) Higher compression ratio can be used with biogas.8) Plants capital cost is low.9) Domestic fuels for burners used in kitchen.10) No toxic to skin.
BENEFITS OF BIOGAS
A study released at the NGV Conference highlights the benefits of using biogas as a source of fuel for NGVs. Biogas consists primarily of methane and is given off in places where decaying organic material is found. According to the report, one of the primary benefits of capturing biogas generated at landfill sites, sewage waste treatment plants, and animal feedlots would be a substantial reduction in greenhouse gas emissions. The report also finds that capturing and burning biogas would provide significant reductions in toxic emissions and ozone forming pollutants, and lower particulate emissions in the case of heavy-duty vehicles. In addition, the report finds that water quality could be improved as a result of reduced waste runoff near sites where biogas is captured and used in NGVs.
The potential reductions of greenhouse gas emissions presented in this paper are staggering. Much of this benefit is derived from capturing and burning methane emissions that currently are released into the atmosphere. The report indicates that an NGV using fuel derived from biogas that otherwise would have been vented provides as much benefit as removing six petroleum-fueled vehicles from the nation's highways. Stated differently, use of biogas in NGVs would produce 600 percent less greenhouse gas emissions when compared with using petroleum as a motor fuel.
Using biogas that currently is flared instead of vented would provide about a 100 percent net reduction in greenhouse gas emissions when compared with burning petroleum motor fuel in a similar vehicle. The study also finds that utilization of available supplies of biogas could potentially reduce the motor vehicle-related greenhouse gas emission by more than 340 million tons -- a 23 percent reduction in overall emissions of motor vehicle greenhouse gas emissions.
The amount of natural gas that potentially could be produced from decaying material around the country is substantial. The report indicates that biogas could displace about 6 billion gallons of motor fuel a year, accounting for nearly four percent of all the gasoline and diesel currently used by motor vehicles. The report indicates that some of this biogas can be produced at prices competitive with conventional petroleum fuels. Much of the fuel, however, is not economic at today's fuel prices, but could easily be made economic if the right types of incentives or credits were provided.